Abstract: • Comparison of two methods for soil organic C quantification is presented. • Springer–Klee wet digestion and dry combustion with automated analyser were compared. • Soil samples were collected from three different sites in a Southern Italy area. • Recoveries close to one were observed for whole dataset and for data grouped per site. • The strong agreement between the methods would enable direct comparison of results. Abstract Soil organic carbon (SOC) is the largest carbon pool in the terrestrial biosphere and it is among the most important factors responsible for conservation of soil quality. Automated dry combustion techniques are gradually replacing traditional quantification methods based on wet digestion chemistry. Critical comparison of different methods is fundamental to reevaluate archives of SOC data and accurately assess and model long-term carbon stock variation and should be performed for different soil types and management conditions. Two analytical methods, the Springer–Klee wet digestion and the dry combustion using an automated analyser, were compared for soils typical of a Mediterranean environment in Southern Italy. Soil samples were collected from three sites, at two depths. Soils were fine textured (from clay–loam to clay) with total carbonate ranging from 6.6 to 16.7 g 100 g− 1. SOC content varied from 6.92 to 28.86 g kg− 1 (as average of the two methods), with values and ranges typical of Southern Europe. On average, Springer–Klee method gave slightly higher values and showed greater data variability. This behaviour, in agreement with other studies, can be attributed to the reaction of K2Cr2O7 with other soil constituents and to analytical constraints. Our results suggest high consistency between Springer–Klee and dry combustion techniques and show recoveries close to one both for the whole dataset and for data grouped per experimental site or soil depth. Linear regression equations between the two methods were slightly affected by different soil types (P = 0.0621). The best fitting of the relationship was a linear regression passing through the origin for the whole dataset (Radj2 = 0.965; RPD = 3.41). The strong overall agreement observed between the two methods would enable the direct comparison of new data set with those already existing in Southern Italy for soils with similar characteristics.

Abstract: Crop models are increasingly being used to assess the impacts of future climate change on production and food security. High quality, site-specific data on weather, soils, management, and cultivar are needed for those model applications. Also important is that model development, evaluation, improvement, and calibration require additional high quality, site-specific measurements on crop yield, growth, phenology, and ancillary traits. We review the evolution of minimum data set requirements for agroecosystem modeling and then describe the characteristics and ranking of sentinel site data needed for crop model improvement, calibration, and application. We in the Agricultural Model Intercomparison and Improvement Project (AgMIP), propose to rank sentinel site data sets as platinum, gold, silver, and copper, based on the degree of true site-specific measurement of weather, soils, management, crop yield, as well as the quality, comprehensiveness, quantity, accuracy, and value. For example, to be ranked platinum, the weather and soil characterization must be measured on-site, and all management inputs must be known. Dataset ranking will be lower for weather measured off-site or soil traits estimated from soil mapping. Ranking also depends on the intended purposes for data use. If the purpose is to improve a crop model for response to water or N, then additional observations are necessary, such as initial soil water, initial soil inorganic N, and plant N uptake during the growing season to be ranked platinum. Rankings are enhanced by presence of multiple treatments and sites. Examples of platinum-, gold-, and silver-quality data sets for model improvement and calibration uses are illustrated.