Abstract: HERMES is a widely used agricultural system model; however, it has never been tested for simulating N loss to subsurface drainage. Here, we integrated a simple drain flbw component into HERMES. We then compared the predictions to four years of data (2002-2005) from central Iowa fields in corn-oybean with winter rye as a cover crop (CC) and without winter rye (NCC). We also compared the HERMES predictions to the more complex Root Zone Water Quality Model (RZWQM) predictions for the same dataset. The average annual observed and simulated N loss to drain flow were 43.8 and 44.4 kg N/ha (NCC) and 17.6 and 18.9 kg N/ha (CC). The slightly over predicted N loss for CC was because of over predicted nitrate concentration, which may be partly caused by slightly under predicted average annual rye shoot N (observed and simulated values were 47.8 and 46.0 kg N/ha). Also, recent research from the site suggests that the soil field capacity may be greater in CC while we used the same soil parameters for both treatments. A local sensitivity analysis suggests that increased field capacity affects HERMES simulations, which includes reduced drain flow nitrate concentrations, increased denitrification, and reduced drain flow volume. HERMES-simulated cumulative monthly drain flow and annual drain flow were reasonable compared to field data and HERMES performance was comparable to other published drainage model tests. Unlike the RZWQM simulations, however, the modified HERMES did riot accurately simulate the year to year variability in nitrate concentration difference between NCC and CC, possibly due in part to the lack of partial mixing and displacement of the soil solution. The results suggest that 1) the relatively simple model HERMES is a promising tool to estimate annual N loss to drain flow under corn-soybean rotations with winter rye as a cover crop and 2) soil field capacity is a critical parameter to investigate to more thoroughly understand and appropriately model denitrification and N losses to subsurface drainage. Published by Elsevier B.V.

Abstract: Agro-meteorological quantities are often in the form of time series, and knowledge about their temporal scaling properties is fundamental for transferring locally measured fluctuations to larger scales and vice versa. However, the scaling analysis of these quantities is complicated due to the presence of localized trends and nonstationarities. The objective of this study was to characterise scaling properties (i.e. statistical self-similarity) of the chosen agro-meteorological quantities through multifractal detrended fluctuation analysis (MFDFA). For this purpose, MFDFA was performedwith 11 322 measured time series (31 yr) of daily air temperature, wind velocity, relative air humidity, global radiation and precipitation from stations located in Finland, Germany, Poland and Spain. The empirical singularity spectra indicated their multifractal structure. The richness of the studied multifractals was evaluated by the width of their spectrum, indicating considerable differences in dynamics and development. In log-log plots of the cumulative distributions of all meteorological parameters the linear functions prevailed for high values of the response, indicating that these distributions were consistent with power-law asymptotic behaviour. Additionally, we investigated the type of multifractality that underlies the q-dependence of the generalized Hurst exponent by analysing the corresponding shuffled and surrogate time series. For most of the studied meteorological parameters, the multifractality is due to different long-range correlations for small and large fluctuations. Only for precipitation does the multifractality result mainly from broad probability function. This feature may be especially valuable for assessing the effect of change in climate dynamics.