Abstract: The DNDC, LandscapeDNDC and IAP-N-GAS models have been designed to simulate the carbon and nitrogen processes of terrestrial ecosystems. Until now, a comparison of these models using simultaneous observations has not been reported, although such a comparison is essential for further model development and application. This study aimed to evaluate the performance of the models, delineate the strengths and limitations of each model for simulating soil nitrous oxide (N2O) and nitric oxide (NO) emissions, and explore short-comings of these models that may require reconsideration. We conducted comparisons among the models using simultaneous observations of both gases and relevant variables from the winter wheat-summer maize rotation system at three field sites with calcareous soils. Simulations of N2O and NO emissions by the three models agreed well with annual observations, but not with daily observations. All models failed to correctly simulate soil moisture, which could explain some of the incorrect daily fluxes of N2O and NO, especially for intensive fluxes during the growing season. Multi-model ensembles are promising approaches to better simulate daily gas emissions. IAP-N-GAS underestimated the priming effect of straw incorporation on N2O and NO emissions, but better results were obtained with DNDC95 and LandscapeDNDC. LandscapeDNDC and IAP-N-GAS need to improve the simulation of irrigation water allocation and residue decomposition processes, respectively, and together to distinguish different irrigation methods as DNDC95 does. All three models overestimated the emissions of the nitrogenous gases for high nitrogen fertilizer (>430 kg N ha(-1) yr(-1)) addition treatments, and therefore, future research should focus more on the simulation of the limitation of soil dissolvable organic carbon on denitrification in calcareous soils.

Abstract: Modelling N transformations within cropping systems is crucial for N management optimization in order to increase N use efficiency and reduce N losses. Such modelling remains challenging because of the complexity of N cycling in soil–plant systems. In the current study, the uncertainties of six widely used process-based models (PBMs), including APSIM, CROPSYST, DAISY, FASSET, HERMES and STICS, were tested in simulating different N managements (catch crops (CC) and different N fertilizer rates) in 12-year rotations in Western Europe. Winter wheat, sugar beet and pea were the main crops, and radish was the main CC in the tested systems. Our results showed that PBMs simulated yield, aboveground biomass, N export and N uptake well with low RMSE values, except for sugar beet, which was generally less well parameterized. Moreover, PBMs provided more accurate crop simulations (i.e. N export and N uptake) compared to simulations of soil (N mineralization and soil mineral N (SMN)) and environmental variables (N leaching). The use of multi-model ensemble mean or median of four PBMs significantly reduced the mean absolute percentage error (MAPE) between simulations and observations to less than 15% for yield, aboveground biomass, N export and N uptake. Multi-model ensemble also significantly reduced the MAPE for net N mineralization and annual N leaching to around 15%, while it was larger than 20% for SMN. Generally, PBMs well simulated the CC effects on N fluxes, i.e. increasing N mineralization and reducing N leaching in both short-term and long-term, and all PBMs correctly predicted the effects of the reduced N rate on all measured variables in the study. The uncertainties of multi-model ensemble for N mineralization, SMN and N leaching were larger, mainly because these variables are influenced by plant-soil interactions and subject to cumulative long-term effects in crop rotations, which makes them more difficult to simulate. Large differences existed between individual PBMs due to the differences in formalisms for describing N processes in soil–plant systems, the skills of modelers and the model calibration level. In addition, the model performance also depended on the simulated variables, for instance, HERMES and FASSET performed better for yield and crop biomass, APSIM, DAISY and STICS performed better for N export and N uptake, STICS provided best simulation for SMN and N leaching among the six individual PBMs in the study, but all PBMs met difficulties to well predict either average or variance of soil N mineralization. Our results showed that better calibration for soil N variables is needed to improve model predictions of N cycling in order to optimize N management in crop rotations.

Abstract: We consider predictions of the impact of climate warming on rice development times in Sri Lanka. The major emphasis is on the uncertainty of the predictions, and in particular on the estimation of mean squared error of prediction. Three contributions to mean squared error are considered. The first is parameter uncertainty that results from model calibration. To take proper account of the complex data structure, generalized least squares is used to estimate the parameters and the variance-covariance matrix of the parameter estimators. The second contribution is model structure uncertainty, which we estimate using two different models. An ANOVA analysis is used to separate the contributions of parameter and model uncertainty to mean squared error. The third contribution is model error, which is estimated using hindcasts. Mean squared error of prediction of time from emergence to maturity, for baseline +2 °C, is estimated as 108 days2, with model error contributing 86 days2, followed by model structure uncertainty which contributes 15 days2 and parameter uncertainty which contributes 7 days2. We also show how prediction uncertainty is reduced if prediction concerns development time averaged over years, or the difference in development time between baseline and warmer temperatures.