Abstract: Soils are a significant source for the secondary greenhouse gas NO and assumed to be a significant source of tropospheric NOx in rural areas. Here we tested the LandscapeDNDC model for its capability to simulate magnitudes and dynamics of soil NO emissions for 22 sites differing in land use (arable, grassland and forest) and edaphic as well as climatic conditions. Overall, LandscapeDNDC simulated mean soil NO emissions agreed well with observations (r(2) = 0.82). However, simulated day to day variations of NO did only agree weakly with high temporal resolution measurements, though agreement between simulations and measurements significantly increased if data were aggregated to weekly, monthly and seasonal time scales. The model reproduced NO emissions from high and low emitting sites, and responded to fertilization (mineral and organic) events with pulse emissions. After evaluation, we linked the LandscapeDNDC model to a GIS database holding spatially explicit data on climate, land use, soil and management to quantify the contribution of soil biogenic NO emissions to the total NOx budget for the State of Saxony, Germany. Our calculations show that soils of both agricultural and forest systems are significant sources and contribute to about 8% (uncertainty range: 6 -13%) to the total annual tropospheric NO, budget for Saxony. However, the contributions of soil NO emission to total tropospheric NO, showed a high spatial variability and in some rural regions such as the Ore Mts., simulated soil NO emissions were by far more important than anthropogenic sources. (C) 2016 Elsevier Ltd. All rights reserved.

Abstract: Agronomic research is important to identify suitable options for improving soil carbon (C) sequestration and reducing soil CO2 emissions. Therefore, the objectives of this study were i) to analyse the on-farm effects of different nitrogen fertilization sources on soil respiration, ii) to explore the effect of fertilization on soil respiration sensitivity to soil temperature (T) and iii) to assess the effect of the different fertilization regimes on the soil C balance. We hypothesized that i) the soil CO2 emission dynamics in Mediterranean irrigated cropping systems were mainly affected by fertilization management and T and ii) fertilization affected the soil C budget via different C inputs and CO2 efflux. Four fertilization systems (farmyard manure, cattle slurry, cattle slurry + mineral, and mineral) were compared in a double-crop rotation based on silage maize (Zea mays L.) and a mixture of Italian ryegrass (Lolium multiflorum Lam.) and oats (Avena sativa L.). The research was performed in the dairy district of Arborea, in the coastal zone of Sardinia (Italy), from May 2011 to May 2012. The soil was a Psammentic Palexeralfs with a sandy texture (940 g sand kg− 1). The soil total respiration (SR), heterotrophic respiration (Rh), T and soil water content (SWC) were simultaneously measured in situ. The soil C balance was computed considering the Rh C losses and the soil C inputs from fertilizer and crop residues. The results showed that the maximum soil CO2 emission rates soon after the application of organic fertilizer reached values up to 12 μmol m− 2 s− 1. On average, the manure fertilizer showed significantly higher CO2 emissions, which resulted in a negative annual C balance (− 2.9 t ha− 1). T also affected the soil respiration temporal dynamics during the summer, consistently with results obtained in other temperate climatic regions that are characterized by wet summers and contrary to results from rainfed Mediterranean systems where the summer SR and Rh are constrained by the low SWC. The sensitivity of soil respiration to temperature significantly increased with C input from fertilizer. In conclusion, this research supported the hypotheses tested. Furthermore, the results indicated that i) soil CO2 efflux was significantly affected by fertilization management and T, and ii) fertilization with manure increased the soil respiration and resulted in a significantly negative soil C budget. This latter finding could be primarily explained by a reduction in productivity and, consequently, in crop residue with organic fertilization alone as compared to mineral, by the favourable SWC and T for mineralization, and by the sandy soil texture, which hindered the formation of macroaggregates and hence soil C stabilization, making fertilizer organic inputs highly susceptible to mineralization.

Abstract: Agronomic research is important to identify suitable options for improving soil carbon (C) sequestration and reducing soil CO2 emissions. Therefore, the objectives of this study were i) to analyse the on-farm effects of different nitrogen fertilization sources on soil respiration, ii) to explore the effect of fertilization on soil respiration sensitivity to soil temperature (T) and iii) to assess the effect of the different fertilization regimes on the soil C balance. We hypothesized that i) the soil CO2 emission dynamics in Mediterranean irrigated cropping systems were mainly affected by fertilization management and T and ii) fertilization affected the soil C budget via different C inputs and CO2 efflux. Four fertilization systems (farmyard manure, cattle slurry, cattle slurry + mineral, and mineral) were compared in a double-crop rotation based on silage maize (Zea mays L) and a mixture of Italian ryegrass (Lolium multiflorum Lam.) and oats (Avena sativa L). The research was performed in the dairy district of Arborea, in the coastal zone of Sardinia (Italy), from May 2011 to May 2012. The soil was a Psammentic Palexeralfs with a sandy texture (940 g sand kg(-1)). The soil total respiration (SR), heterotrophic respiration (Rh), T and soil water content (SWC) were simultaneously measured in situ. The soil C balance was computed considering the Rh C losses and the soil C inputs from fertilizer and crop residues. The results showed that the maximum soil CO2 emission rates soon after the application of organic fertilizer reached values up to 121,1111 1 111(-2) s(-1). On average, the manure fertilizer showed significantly higher CO2 emissions, which resulted in a negative annual C balance (-2.9 t ha(-1)). T also affected the soil respiration temporal dynamics during the summer, consistently with results obtained in other temperate climatic regions that are characterized by wet summers and contrary to results from rainfed Mediterranean systems where the summer SR and Rh are constrained by the low SWC. The sensitivity of soil respiration to temperature significantly increased with C input from fertilizer. In conclusion, this research supported the hypotheses tested. Furthermore, the results indicated that i) soil CO2 efflux was significantly affected by fertilization management and T, and ii) fertilization with manure increased the soil respiration and resulted in a significantly negative soil C budget. This latter finding could be primarily explained by a reduction in productivity and, consequently, in crop residue with organic fertilization alone as compared to mineral, by the favourable SWC and T for mineralization, and by the sandy soil texture, which hindered the formation of macroaggregates and hence soil C stabilization, making fertilizer organic inputs highly susceptible to mineralization. (C) 2016 Elsevier B.V. All rights reserved.