Abstract: • Comparison of two methods for soil organic C quantification is presented. • Springer–Klee wet digestion and dry combustion with automated analyser were compared. • Soil samples were collected from three different sites in a Southern Italy area. • Recoveries close to one were observed for whole dataset and for data grouped per site. • The strong agreement between the methods would enable direct comparison of results. Abstract Soil organic carbon (SOC) is the largest carbon pool in the terrestrial biosphere and it is among the most important factors responsible for conservation of soil quality. Automated dry combustion techniques are gradually replacing traditional quantification methods based on wet digestion chemistry. Critical comparison of different methods is fundamental to reevaluate archives of SOC data and accurately assess and model long-term carbon stock variation and should be performed for different soil types and management conditions. Two analytical methods, the Springer–Klee wet digestion and the dry combustion using an automated analyser, were compared for soils typical of a Mediterranean environment in Southern Italy. Soil samples were collected from three sites, at two depths. Soils were fine textured (from clay–loam to clay) with total carbonate ranging from 6.6 to 16.7 g 100 g− 1. SOC content varied from 6.92 to 28.86 g kg− 1 (as average of the two methods), with values and ranges typical of Southern Europe. On average, Springer–Klee method gave slightly higher values and showed greater data variability. This behaviour, in agreement with other studies, can be attributed to the reaction of K2Cr2O7 with other soil constituents and to analytical constraints. Our results suggest high consistency between Springer–Klee and dry combustion techniques and show recoveries close to one both for the whole dataset and for data grouped per experimental site or soil depth. Linear regression equations between the two methods were slightly affected by different soil types (P = 0.0621). The best fitting of the relationship was a linear regression passing through the origin for the whole dataset (Radj2 = 0.965; RPD = 3.41). The strong overall agreement observed between the two methods would enable the direct comparison of new data set with those already existing in Southern Italy for soils with similar characteristics.

Abstract: A field experiment was conducted in Southern Italy to evaluate the effects of different water quality and fertilizers on yield performance of tomato crop. In mineral nitrogen (N) fertilizer and irrigation with fresh water (Electrical Conductivity, EC, = 0.9 dS m⁻¹) (FWF); mineral N fertilizer and irrigation with saline water (EC = 6.0 dS m⁻¹) (SWF); municipal solid waste (MSW) compost and irrigation with fresh water (EC = 0.9 dS m⁻¹) (FWC); MSW compost and irrigation with saline water (EC = 6.0 dS m⁻¹) (SWC). At harvest, weight and number of fruits and refractometric index (°Brix) were measured, total and marketable yield and dry matter of fruit were calculated. The results indicated that MSW compost, applied as amendment, could substitute the mineral fertilizer. In fact, in the treatments based on compost application, the tomato average marketable yield increased by 9% compared with treatments with mineral fertilizer. The marketable yield in the SWF and SWC treatments (with an average soil EC in two years to about 3.5 dS m⁻¹) decreased respectively of 20 and 10%, in respect to fresh water treatments. At the end of the experiment, application of compost significantly decreased the sodium absorption rate (SAR) of SWC treatment in respect of SWF (−29.9%). Significant differences were observed among the four treatments both on soil solution cations either exchangeable cations. In particular compost application increased the calcium (Ca) and potassium (K) contents in saturated soil paste respect to the SWF ones (31.4% and 59.5%, respectively). At the same time saturated soil paste sodium (Na) in SWC treatment recorded a decrease of 17.4% compared to SWF.

Abstract: The objective of this work was to evaluate the suitability of carbohydrates and amino compounds in soil and soil organic matter (SOM) fractions to depict the management-induced changes in soil over short-term course. Soil samples were collected from two experimental fields managed according to organic farming regulations and a sequential fractionation procedure was applied to separate the light fraction (LF), particulate organic matter (POM), and mobile humic acid (MHA). Contents of carbohydrates and amino compounds were determined in soil and correspondent SOM fractions. Over a 2-year course, carbohydrate contents decreased in the LF fraction while it increased noticeably in the POM and slightly in the MHA fractions leading into questioning whether decomposing materials get incorporated into older fractions. Amino N content constituted up to 30% of total soil N, with a major contribution of the humic fraction (MHA). Although the LF, POM, and MHA fractions showed the greatest amino N content after the compost-legumes combinations, the carbohydrate and amino N contents in the POM and MHA fractions of the unamended soil increased as large as the corresponding fertilized plots, underlining that conservative soil management results in accumulation of labile forms of soil C and N that consequently might build up soil fertility. The changes after different treatments suggest the suitability of carbohydrates and amino compounds as short-term indicators for soil management.