Abstract: Highlights • New method to investigate biogeochemical model structure performance. • Process based hydrological modelling can improve biogeochemical model predictions. • Modelling efficiency dramatically drops with multiple objectives. Abstract This work presents a novel way for assessing and comparing different hydro-biogeochemical model structures and their performances. We used the LandscapeDNDC modelling framework to set up four models of different complexity, considering two soil-biogeochemical and two hydrological modules. The performance of each model combination was assessed using long-term (8 years) data and applying different thresholds, considering multiple criteria and objective functions. Our results show that each model combination had its strength for particular criteria. However, only 0.01% of all model runs passed the complete rejectionist framework. In contrast, our comparatively applied assessments of single thresholds, as frequently used in other studies, lead to a much higher acceptance rate of 40–70%. Therefore, our study indicates that models can be right for the wrong reasons, i.e., matching GHG emissions while at the same time failing to simulate other criteria such as soil moisture or plant biomass dynamics.

Abstract: In this study we quantify regional parameter-induced model uncertainty on nitrous oxide (N2O) emissions and nitrate (NO3) leaching from arable soils of Saxony (Germany) using the biogeochemical model LandscapeDNDC. For this we calculate a regional inventory using a joint parameter distribution for key parameters describing microbial C and N turnover processes as obtained by a Bayesian calibration study. We representatively sampled 400 different parameter vectors from the discrete joint parameter distribution comprising approximately 400,000 parameter combinations and used these to calculate 400 individual realizations of the regional inventory. The spatial domain (represented by 4042 polygons) is set up with spatially explicit soil and climate information and a region-typical 3-year crop rotation consisting of winter wheat, rape- seed, and winter barley. Average N2O emission from arable soils in the state of Saxony across all 400 realizations was 1.43 ± 1.25 [kg N / ha] with a median value of 1.05 [kg N / ha]. Using the default IPCC emission factor approach (Tier 1) for direct emissions reveal a higher average N2O emission of 1.51 [kg N / ha] due to fertilizer use. In the regional uncertainty quantification the 20% likelihood range for N2O emissions is 0.79 – 1.37 [kg N / ha] (50% likelihood: 0.46 – 2.05 [kg N / ha]; 90% likelihood: 0.11 – 4.03 [kg N / ha]). Respective quantities were calculated for nitrate leaching.

Abstract: Soils are a significant source for the secondary greenhouse gas NO and assumed to be a significant source of tropospheric NOx in rural areas. Here we tested the LandscapeDNDC model for its capability to simulate magnitudes and dynamics of soil NO emissions for 22 sites differing in land use (arable, grassland and forest) and edaphic as well as climatic conditions. Overall, LandscapeDNDC simulated mean soil NO emissions agreed well with observations (r(2) = 0.82). However, simulated day to day variations of NO did only agree weakly with high temporal resolution measurements, though agreement between simulations and measurements significantly increased if data were aggregated to weekly, monthly and seasonal time scales. The model reproduced NO emissions from high and low emitting sites, and responded to fertilization (mineral and organic) events with pulse emissions. After evaluation, we linked the LandscapeDNDC model to a GIS database holding spatially explicit data on climate, land use, soil and management to quantify the contribution of soil biogenic NO emissions to the total NOx budget for the State of Saxony, Germany. Our calculations show that soils of both agricultural and forest systems are significant sources and contribute to about 8% (uncertainty range: 6 -13%) to the total annual tropospheric NO, budget for Saxony. However, the contributions of soil NO emission to total tropospheric NO, showed a high spatial variability and in some rural regions such as the Ore Mts., simulated soil NO emissions were by far more important than anthropogenic sources. (C) 2016 Elsevier Ltd. All rights reserved.