Abstract: Purpose The study aimed to describe the carbohydrates and amino compounds content in soil, the light fraction (LF), the >53 μm particulate organic matter (POM), and the mobile humic acid (MHA) fraction and to find out whether the carbohydrates and amino compounds can be used to explain the origin of SOM fractions. Materials and methods Soil samples were collected from two agricultural fields managed under organic farming in southern Italy. The LF, the POM, and the MHA were sequentially extracted from each soil sample then characterized. Seven neutral sugars and 19 amino compounds (amino acids and amino sugars) were determined in each soil sample and its correspondent fractions. Results and discussion The MHA contained less carbohydrate than the LF or the POM but its carbohydrates, although dominated by arabinose, were relatively with larger microbial contribution as revealed by the mannose/xylose ratio. The amino compounds were generally less in the LF or the POM than in the MHA, while the fungal (aspartic and serine) and bacterial (alanine and glycine) amino acids were larger in the MHA than in the LF or the POM, underlining the microbial contribution to the MHA. Results from both sites indicated that total carbohydrates content decreased moving from the LF (younger fraction) to the MHA (older fraction), which seems to follow a decomposition continuum of organic matter in the soil-plant system. Conclusions The study showed that the MHA is a labile humified fraction of soil C due to its content of carbohydrates and concluded that the content of carbohydrates and amino compounds in the LF, the POM and the MHA can depict the nature of these fractions and their cycling pattern and response to land management.

Abstract: This paper summarizes currently available data on greenhouse gas (GHG) emissions from African natural ecosystems and agricultural lands. The available data are used to synthesize current understanding of the drivers of change in GHG emissions, outline the knowledge gaps, and suggest future directions and strategies for GHG emission research. GHG emission data were collected from 75 studies conducted in 22 countries (n = 244) in sub-Saharan Africa (SSA). Carbon dioxide (CO2) emissions were by far the largest contributor to GHG emissions and global warming potential (GWP) in SSA natural terrestrial systems. CO2 emissions ranged from 3.3 to 57.0 Mg CO2 ha(-1) yr(-1), methane (CH4) emissions ranged from -4.8 to 3.5 kg ha(-1) yr(-1) (-0.16 to 0.12 Mg CO2 equivalent (eq.) ha(-1) yr(-1)), and nitrous oxide (N2O) emissions ranged from -0.1 to 13.7 kg ha(-1) yr(-1) (-0.03 to 4.1 Mg CO2 eq. ha(-1) yr(-1)). Soil physical and chemical properties, rewetting, vegetation type, forest management, and land-use changes were all found to be important factors affecting soil GHG emissions from natural terrestrial systems. In aquatic systems, CO2 was the largest contributor to total GHG emissions, ranging from 5.7 to 232.0 Mg CO2 ha(-1) yr(-1), followed by -26.3 to 2741.9 kgCH(4) ha(-1) yr(-1) (-0.89 to 93.2 Mg CO2 eq. ha(-1) yr(-1)) and 0.2 to 3.5 kg N2O ha(-1) yr(-1) (0.06 to 1.0 Mg CO2 eq. ha(-1) yr(-1)). Rates of all GHG emissions from aquatic systems were affected by type, location, hydrological characteristics, and water quality. In croplands, soil GHG emissions were also dominated by CO2, ranging from 1.7 to 141.2 Mg CO2 ha(-1) yr(-1), with -1.3 to 66.7 kgCH(4) ha(-1) yr(-1) (-0.04 to 2.3 Mg CO2 eq. ha(-1) yr(-1)) and 0.05 to 112.0 kg N2O ha(-1) yr(-1) (0.015 to 33.4 Mg CO2 eq. ha(-1) yr(-1)). N2O emission factors (EFs) ranged from 0.01 to 4.1 %. Incorporation of crop residues or manure with inorganic fertilizers invariably resulted in significant changes in GHG emissions, but results were inconsistent as the magnitude and direction of changes were differed by gas. Soil GHG emissions from vegetable gardens ranged from 73.3 to 132.0 Mg CO2 ha(-1) yr(-1) and 53.4 to 177.6 kg N2O ha(-1) yr(-1) (15.9 to 52.9 Mg CO2 eq. ha(-1) yr(-1)) and N2O EFs ranged from 3 to 4 %. Soil CO2 and N2O emissions from agroforestry were 38.6 Mg CO2 ha(-1) yr(-1) and 0.2 to 26.7 kg N2O ha(-1) yr(-1) (0.06 to 8.0 Mg CO2 eq. ha(-1) yr(-1)), respectively. Improving fallow with nitrogen (N)-fixing trees led to increased CO2 and N2O emissions compared to conventional croplands. The type and quality of plant residue in the fallow is an important control on how CO2 and N2O emissions are affected. Throughout agricultural lands, N2O emissions slowly increased with N inputs below 150 kg N ha(-1) yr(-1) and increased exponentially with N application rates up to 300 kg N ha(-1) yr(-1). The lowest yield-scaled N2O emissions were reported with N application rates ranging between 100 and 150 kg N ha(-1). Overall, total CO2 eq. emissions from SSA natural ecosystems and agricultural lands were 56.9 +/- 12.7 x 10(9) Mg CO2 eq. yr(-1) with natural ecosystems and agricultural lands contributing 76.3 and 23.7 %, respectively. Additional GHG emission measurements are urgently required to reduce uncertainty on annual GHG emissions from the different land uses and identify major control factors and mitigation options for low-emission development. A common strategy for addressing this data gap may include identifying priorities for data acquisition, utilizing appropriate technologies, and involving international networks and collaboration.

Abstract: As planetary boundaries are rapidly being approached, humanity has little room for additional expansion and conventional intensification of agriculture, while a growing world population further spreads the food gap. Ample evidence exists that improved on-farm water management can close water-related yield gaps to a considerable degree, but its global significance remains unclear. In this modeling study we investigate systematically to what extent integrated crop water management might contribute to closing the global food gap, constrained by the assumption that pressure on water resources and land does not increase. Using a process-based bio-/agrosphere model, we simulate the yield-increasing potential of elevated irrigation water productivity (including irrigation expansion with thus saved water) and optimized use of in situ precipitation water (alleviated soil evaporation, enhanced infiltration, water harvesting for supplemental irrigation) under current and projected future climate (from 20 climate models, with and without beneficial CO2 effects). Results show that irrigation efficiency improvements can save substantial amounts of water in many river basins (globally 48% of non-productive water consumption in an ‘ambitious’ scenario), and if rerouted to irrigate neighboring rainfed systems, can boost kcal production significantly (26% global increase). Low-tech solutions for small-scale farmers on water-limited croplands show the potential to increase rainfed yields to a similar extent. In combination, the ambitious yet achievable integrated water management strategies explored in this study could increase global production by 41% and close the water-related yield gap by 62%. Unabated climate change will have adverse effects on crop yields in many regions, but improvements in water management as analyzed here can buffer such effects to a significant degree.