Abstract: The accurate estimation of crop grain nitrogen (N; N in grain yield) is crucial for optimizing agricultural N management, especially in crop rotations. In the present study, 12 process-based models were applied to simulate the grain N of i) seven crops in rotations, ii) across various pedo-climatic and agro-management conditions in Europe, under both continuous simulation and single year simulation, and for iv) two calibration levels, namely minimal and detailed calibration. Generally, the results showed that the accuracy of the simulations in predicting grain N increased under detailed calibration. The models performed better in predicting the grain N of winter wheat (Triticum aestivum L.), winter barley (Hordewn vulgare L.) and spring barley (Hordeum vulgare L.) compared to spring oat (Avena saliva L.), winter rye (Secale cereale L.), pea (Piswn sativum L.) and winter oilseed rape (Brassica napus L.). These differences are linked to the intensity of parameterization with better parameterized crops showing lower prediction errors. The model performance was influenced by N fertilization and irrigation treatments, and a majority of the predictions were more accurate under low N and rainfed treatments. Moreover, the multi-model mean provided better predictions of grain N compared to any individual model. In regard to the Individual models, DAISY, FASSET, HERMES, MONICA and STICS are suitable for predicting grain N of the main crops in typical European crop rotations, which all performed well in both continuous simulation and single year simulation. Our results show that both the model initialization and the cover crop effects in crop rotations should be considered in order to achieve good performance of continuous simulation. Furthermore, the choice of either continuous simulation or single year simulation should be guided by the simulation objectives (e.g. grain yield, grain N content or N dynamics), the crop sequence (inclusion of legumes) and treatments (rate and type of N fertilizer) included in crop rotations and the model formalism.

Abstract: Crop productivity and water consumption form the basis to calculate the water footprint (WF) of a specific crop. Under current climate conditions, calculated evapotranspiration is related to observed crop yields to calculate WF. The assessment of WF under future climate conditions requires the simulation of crop yields adding further uncertainty. To assess the uncertainty of model based assessments of WF, an ensemble of crop models was applied to data from five field experiments across Europe. Only limited data were provided for a rough calibration, which corresponds to a typical situation for regional assessments, where data availability is limited. Up to eight models were applied for wheat. The coefficient of variation for the simulated actual evapotranspiration between models was in the range of 13%–19%, which was higher than the inter-annual variability. Simulated yields showed a higher variability between models in the range of 17%–39%. Models responded differently to elevated CO2 in a FACE (Free-Air Carbon Dioxide Enrichment) experiment, especially regarding the reduction of water consumption. The variability of calculated WF between models was in the range of 15%–49%. Yield predictions contributed more to this variance than the estimation of water consumption. Transpiration accounts on average for 51%–68% of the total actual evapotranspiration.

Abstract: • Comparison of two methods for soil organic C quantification is presented. • Springer–Klee wet digestion and dry combustion with automated analyser were compared. • Soil samples were collected from three different sites in a Southern Italy area. • Recoveries close to one were observed for whole dataset and for data grouped per site. • The strong agreement between the methods would enable direct comparison of results. Abstract Soil organic carbon (SOC) is the largest carbon pool in the terrestrial biosphere and it is among the most important factors responsible for conservation of soil quality. Automated dry combustion techniques are gradually replacing traditional quantification methods based on wet digestion chemistry. Critical comparison of different methods is fundamental to reevaluate archives of SOC data and accurately assess and model long-term carbon stock variation and should be performed for different soil types and management conditions. Two analytical methods, the Springer–Klee wet digestion and the dry combustion using an automated analyser, were compared for soils typical of a Mediterranean environment in Southern Italy. Soil samples were collected from three sites, at two depths. Soils were fine textured (from clay–loam to clay) with total carbonate ranging from 6.6 to 16.7 g 100 g− 1. SOC content varied from 6.92 to 28.86 g kg− 1 (as average of the two methods), with values and ranges typical of Southern Europe. On average, Springer–Klee method gave slightly higher values and showed greater data variability. This behaviour, in agreement with other studies, can be attributed to the reaction of K2Cr2O7 with other soil constituents and to analytical constraints. Our results suggest high consistency between Springer–Klee and dry combustion techniques and show recoveries close to one both for the whole dataset and for data grouped per experimental site or soil depth. Linear regression equations between the two methods were slightly affected by different soil types (P = 0.0621). The best fitting of the relationship was a linear regression passing through the origin for the whole dataset (Radj2 = 0.965; RPD = 3.41). The strong overall agreement observed between the two methods would enable the direct comparison of new data set with those already existing in Southern Italy for soils with similar characteristics.