Abstract: Soils are a significant source for the secondary greenhouse gas NO and assumed to be a significant source of tropospheric NOx in rural areas. Here we tested the LandscapeDNDC model for its capability to simulate magnitudes and dynamics of soil NO emissions for 22 sites differing in land use (arable, grassland and forest) and edaphic as well as climatic conditions. Overall, LandscapeDNDC simulated mean soil NO emissions agreed well with observations (r(2) = 0.82). However, simulated day to day variations of NO did only agree weakly with high temporal resolution measurements, though agreement between simulations and measurements significantly increased if data were aggregated to weekly, monthly and seasonal time scales. The model reproduced NO emissions from high and low emitting sites, and responded to fertilization (mineral and organic) events with pulse emissions. After evaluation, we linked the LandscapeDNDC model to a GIS database holding spatially explicit data on climate, land use, soil and management to quantify the contribution of soil biogenic NO emissions to the total NOx budget for the State of Saxony, Germany. Our calculations show that soils of both agricultural and forest systems are significant sources and contribute to about 8% (uncertainty range: 6 -13%) to the total annual tropospheric NO, budget for Saxony. However, the contributions of soil NO emission to total tropospheric NO, showed a high spatial variability and in some rural regions such as the Ore Mts., simulated soil NO emissions were by far more important than anthropogenic sources. (C) 2016 Elsevier Ltd. All rights reserved.

Abstract: This paper summarizes currently available data on greenhouse gas (GHG) emissions from African natural ecosystems and agricultural lands. The available data are used to synthesize current understanding of the drivers of change in GHG emissions, outline the knowledge gaps, and suggest future directions and strategies for GHG emission research. GHG emission data were collected from 75 studies conducted in 22 countries (n = 244) in sub-Saharan Africa (SSA). Carbon dioxide (CO2) emissions were by far the largest contributor to GHG emissions and global warming potential (GWP) in SSA natural terrestrial systems. CO2 emissions ranged from 3.3 to 57.0 Mg CO2 ha(-1) yr(-1), methane (CH4) emissions ranged from -4.8 to 3.5 kg ha(-1) yr(-1) (-0.16 to 0.12 Mg CO2 equivalent (eq.) ha(-1) yr(-1)), and nitrous oxide (N2O) emissions ranged from -0.1 to 13.7 kg ha(-1) yr(-1) (-0.03 to 4.1 Mg CO2 eq. ha(-1) yr(-1)). Soil physical and chemical properties, rewetting, vegetation type, forest management, and land-use changes were all found to be important factors affecting soil GHG emissions from natural terrestrial systems. In aquatic systems, CO2 was the largest contributor to total GHG emissions, ranging from 5.7 to 232.0 Mg CO2 ha(-1) yr(-1), followed by -26.3 to 2741.9 kgCH(4) ha(-1) yr(-1) (-0.89 to 93.2 Mg CO2 eq. ha(-1) yr(-1)) and 0.2 to 3.5 kg N2O ha(-1) yr(-1) (0.06 to 1.0 Mg CO2 eq. ha(-1) yr(-1)). Rates of all GHG emissions from aquatic systems were affected by type, location, hydrological characteristics, and water quality. In croplands, soil GHG emissions were also dominated by CO2, ranging from 1.7 to 141.2 Mg CO2 ha(-1) yr(-1), with -1.3 to 66.7 kgCH(4) ha(-1) yr(-1) (-0.04 to 2.3 Mg CO2 eq. ha(-1) yr(-1)) and 0.05 to 112.0 kg N2O ha(-1) yr(-1) (0.015 to 33.4 Mg CO2 eq. ha(-1) yr(-1)). N2O emission factors (EFs) ranged from 0.01 to 4.1 %. Incorporation of crop residues or manure with inorganic fertilizers invariably resulted in significant changes in GHG emissions, but results were inconsistent as the magnitude and direction of changes were differed by gas. Soil GHG emissions from vegetable gardens ranged from 73.3 to 132.0 Mg CO2 ha(-1) yr(-1) and 53.4 to 177.6 kg N2O ha(-1) yr(-1) (15.9 to 52.9 Mg CO2 eq. ha(-1) yr(-1)) and N2O EFs ranged from 3 to 4 %. Soil CO2 and N2O emissions from agroforestry were 38.6 Mg CO2 ha(-1) yr(-1) and 0.2 to 26.7 kg N2O ha(-1) yr(-1) (0.06 to 8.0 Mg CO2 eq. ha(-1) yr(-1)), respectively. Improving fallow with nitrogen (N)-fixing trees led to increased CO2 and N2O emissions compared to conventional croplands. The type and quality of plant residue in the fallow is an important control on how CO2 and N2O emissions are affected. Throughout agricultural lands, N2O emissions slowly increased with N inputs below 150 kg N ha(-1) yr(-1) and increased exponentially with N application rates up to 300 kg N ha(-1) yr(-1). The lowest yield-scaled N2O emissions were reported with N application rates ranging between 100 and 150 kg N ha(-1). Overall, total CO2 eq. emissions from SSA natural ecosystems and agricultural lands were 56.9 +/- 12.7 x 10(9) Mg CO2 eq. yr(-1) with natural ecosystems and agricultural lands contributing 76.3 and 23.7 %, respectively. Additional GHG emission measurements are urgently required to reduce uncertainty on annual GHG emissions from the different land uses and identify major control factors and mitigation options for low-emission development. A common strategy for addressing this data gap may include identifying priorities for data acquisition, utilizing appropriate technologies, and involving international networks and collaboration.

Abstract: In this article, we evaluate and compare results from three integrated assessment models (GCAM, IMAGE, and ReMIND/MAgPIE) regarding the drivers and impacts of bioenergy production on the global land system. The considered model frameworks employ linked energy, economy, climate and land use modules. By the help of these linkages the direct competition of bioenergy with other energy technology options for greenhouse gas (GHG) mitigation, based on economic costs and GHG emissions from bioenergy production, has been taken into account. Our results indicate that dedicated bioenergy crops and biomass residues form a potentially important and cost-effective input into the energy system. At the same time, however, the results differ strongly in terms of deployment rates, feedstock composition and land-use and greenhouse gas implications. The current paper adds to earlier work by specific looking into model differences with respect to the land-use component that could contribute to the noted differences in results, including land cover allocation, land use constraints, energy crop yields, and non-bioenergy land mitigation options modeled. In scenarios without climate change mitigation, bioenergy cropland represents 10-18 % of total cropland by 2100 across the different models, and boosts cropland expansion at the expense of carbon richer ecosystems. Therefore, associated emissions from land-use change and agricultural intensification as a result of bio-energy use range from 14 and 113 Gt CO2-eq cumulatively through 2100. Under climate policy, bioenergy cropland increases to 24-36 % of total cropland by 2100.